As Brenden said, you can run 2 sites on the same Kentico instance, one Portal one MVC, not ideal.
But otherwise if you are good with a larger content freeze, it is possible to "Convert" a portal site to an MVC Site in terms of the data. There's only a couple database fields that differentiate an MVC Site from a Portal Site, so you can use this to 'clone' over the portal engine site and make all your content pages "Content-Only" ones.
Theoretically you could then try to write a conversion script to convert widgets and zones to page builder json...but that gets complicated.