Doesn't look like that is the issue here. I compared the web.config to pre-upgrade and the only difference was the addition of this under assemblies:
<add assembly="WindowsBase, Version=4.0.0.0, Culture=neutral, PublicKeyToken=31bf3856ad364e35" />
<add assembly="System.Windows.Forms, Version=4.0.0.0, Culture=neutral, PublicKeyToken=b77a5c561934e089" />
<add assembly="System.Net.Http, Version=2.0.0.0, Culture=neutral, PublicKeyToken=b03f5f7f11d50a3a" />